Decorrelation of the static and dynamic length scales in hard-sphere glass formers.
نویسندگان
چکیده
We show that, in the equilibrium phase of glass-forming hard-sphere fluids in three dimensions, the static length scales tentatively associated with the dynamical slowdown and the dynamical length characterizing spatial heterogeneities in the dynamics unambiguously decorrelate. The former grow at a much slower rate than the latter when density increases. This observation is valid for the dynamical range that is accessible to computer simulations, which roughly corresponds to that accessible in colloidal experiments. We also find that, in this same range, no one-to-one correspondence between relaxation time and point-to-set correlation length exists. These results point to the coexistence of several relaxation mechanisms in the dynamically accessible regime of three-dimensional hard-sphere glass formers.
منابع مشابه
Structure and dynamics of glass formers: predictability at large length scales.
Dynamic heterogeneity in glass formers has been related to their static structure using the concept of dynamic propensity. We reexamine this relationship by analyzing dynamical fluctuations in two atomistic glass formers and two theoretical models. We introduce quantitative statistical indicators which show that the dynamics of individual particles cannot be predicted on the basis of the propen...
متن کاملGeometrical frustration and static correlations in hard-sphere glass formers.
We analytically and numerically characterize the structure of hard-sphere fluids in order to review various geometrical frustration scenarios of the glass transition. We find generalized polytetrahedral order to be correlated with increasing fluid packing fraction, but to become increasingly irrelevant with increasing dimension. We also find the growth in structural correlations to be modest in...
متن کاملHard sphere-like glass transition in eye lens α-crystallin solutions.
We study the equilibrium liquid structure and dynamics of dilute and concentrated bovine eye lens α-crystallin solutions, using small-angle X-ray scattering, static and dynamic light scattering, viscometry, molecular dynamics simulations, and mode-coupling theory. We find that a polydisperse Percus-Yevick hard-sphere liquid-structure model accurately reproduces both static light scattering data...
متن کاملAssessing the role of static length scales behind glassy dynamics in polydisperse hard disks.
The possible role of growing static order in the dynamical slowing down toward the glass transition has recently attracted considerable attention. On the basis of random first-order transition theory, a new method to measure the static correlation length of amorphous order, called "point-to-set" (PTS) length, has been proposed and used to show that the dynamic length grows much faster than the ...
متن کامل‘Unsticking’ a colloidal glass, and sticking it again
We study glass formation in hard spheres with short-range attraction. The system consists of nearly-hard-sphere polymethylmethacrylate particles and non-adsorbing random-coil polystyrene which induced a depletion attraction between the particles. The experiments reveal a re-entrant glass transition and two qualitatively distinct glassy states. Dynamic light scattering, covering eleven orders of...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 87 4 شماره
صفحات -
تاریخ انتشار 2013